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2017
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2017年论文 1 Yang, Jie Liu, Xinhua Tian, Jianliya Ma, Xiao Wang, Baofeng Li, Wenjun Wang, Qigang Adhesive nanocomposites of hypergravity induced Co3O4 nanoparticles and natural gels as Li-ion battery anode materials with high capacitance and low resistance RSC ADVANCES VL 7 IS 34 BP 21061 EP 21067 DI 10.1039/c7ra02725g PD 2017 PY 2017 An adhesive composite of hypergravity induced Co3O4 nanoparticles and natural xanthan gum (XG) was prepared and applied as the anode electrode of a Li-ion battery for the first time. The Co3O4 nanoparticles were hydrothermally prepared and assembled on the water-oil interface with the assistance of hypergravity. The discharge capacity of the final nanocomposite anodes with the xanthan gum binder can reach 742.5 mA h g(-1) after 50 cycles at a charge-discharge rate of 0.5 C, whereas the Co3O4 working electrode with a traditional PVDF binder only displayed a lower capacity of 219.9 mA h g(-1). The addition of the XG binder can improve the electrochemical performance of the hypergravity Co3O4 anode due to its high viscosity, which can relieve the volume expansion of the Co3O4 particles during charge-discharge cycles. What's more, the XG can efficiently transfer Li-ions to the surface of the Co3O4 like polyethylene oxide (PEO) solid electrolytes. 2 Wei, Qingcong Xu, Wei Zhang, Qi Zhang, Shuang Cheng, Liming Wang, Qigang Dynamic hydrogels produced via monoamine oxidase B-catalyzed deamination and aldimine crosslinking for 3D printing JOURNAL OF MATERIALS CHEMISTRY B VL 5 IS 26 BP 5092 EP 5095 DI 10.1039/c7tb01108c PD JUL 14 2017 PY 2017 Dynamic hydrogels were prepared via an oxidative deamination reaction catalyzed by monoamine oxidase B. Amino-containing polysaccharides (or proteins) and oxidative products (aldehydes) formed the dynamic Schiff base linkages, which endowed the hydrogel with excellent self-healing and multiresponsive properties.
3 Ye, Yuemei Xiao, Linlin He, Bin Zhang, Qi Nie, Tao Yang, Xinrui Wu, Dongbei Cheng, Heli Li, Ping Wang, Qigang Oxygen-tuned nanozyme polymerization for the preparation of hydrogels with printable and antibacterial properties JOURNAL OF MATERIALS CHEMISTRY B VL 5 IS 7 BP 1518 EP 1524 DI 10.1039/c6tb03317b PD 2017 PY 2017 Nanozymes merge nanotechnology with biology and provide a lower cost and higher stability options, compared to that of natural enzymes. However, nanozyme catalyzed polymerization under physiological conditions is still a big challenge due to heavy oxygen inhibition. In this study, the simple glucose oxidase system can effectively adjust oxygen concentration and generate hydrogen peroxide, which assists in the realization of nanozyme-catalyzed polymerization. The nanozyme based hydrogel is printable due to its mild preparation with gradually increased viscosity. The antibacterial performance is ascribed to the in situ generated hydroxyl radical via the reaction of the bound nanozyme and glucose. |
版权所有:2017年 同济大学王启刚教授课题组 |