2016年论文

1. Liu, Xinhua

   Yin, Chengyao

   Yang, Jie

   Liang, Meiying

   Wei, Junjie

   Zhang, Ziyang

   Wang, Huanlei

   Wang, Qigang

Controllable preparation of an eggshell membrane supported hydrogel

   electrolyte with thickness-dependent electrochemical performance

JOURNAL OF MATERIALS CHEMISTRY A

VL 4

IS 46

BP 17933

EP 17938

DI 10.1039/c6ta07341g

PD 2016

PY 2016

The preparation of thin gel electrolyte membranes with controllable

   thickness is important to explore the thickness-dependent

   electrochemical behaviors; this can further guide the fabrication of

   energy devices. Here we employ an in situ polymerization method to

   prepare a BSA-PDMAA-SiO2 cross-linked nanocomposite hydrogel on surfaces

   of eggshell membranes, which can be used as integrated separator and

   electrolyte in a supercapacitor after absorbing the electrolyte. The

   novel controlled thickness of the coated hydrogel therefore offers

   superior space utilization essential for all-solid-state devices. The

   composite gel can reach a high ionic conductivity of 8.8 mS cm(-1) and a

   resulting C-sp value of 161 F g(-1) at the current density of 1 A g(-1)

   when assembled in the supercapacitor, while the eggshell membrane based

   device has limited values of 2.7 mS cm(-1) and 88 F g(-1). A new insight

   into hybrid material preparation from low-cost natural life waste is

   presented in this work to obtain high performance gel electrolytes in

   energy devices.

2. Wu, Qing

   Wang, Zhaoqi

   Zhang, Haixia

   Zhu, Rongrong

   Wang, Shilong

   Wang, Qigang

TI Fe3O4@nanogel via UOx/HRP initiated surface polymerization for pH

   sensitive drug delivery

RSC ADVANCES

VL 6

IS 58

BP 53170

EP 53174

DI 10.1039/c6ra06331d

PD 2016

PY 2016

AB This communication describes a new strategy to fabricate a nanogel layer

   around magnetic nanoparticles by surface free-radical polymerization

   triggered by the cascade reaction of urate oxidase and horseradish

   peroxidase, which showed high loading capacity, pH-responsive drug

   release and low cytotoxicity.

3. Wei, Qingcong

   Xu, Mengchi

   Liao, Chuanan

   Wu, Qing

   Liu, Mingyu

   Zhang, Ye

   Wu, Chengtie

   Cheng, Liming

   Wang, Qigang

Printable hybrid hydrogel by dual enzymatic polymerization with

   superactivity

CHEMICAL SCIENCE

VL 7

IS 4

BP 2748

EP 2752

DI 10.1039/c5sc02234g

PD 2016

PY 2016

A new approach has been developed to fabricate tough hybrid hydrogels by

   employing dual enzyme-mediated redox initiation to achieve

   post-self-assembly cross-linking polymerization. The resulting hydrogel

   combines the merits of supramolecular hydrogels with polymeric hydrogels

   to achieve higher mechanical strength and porous networks. Designed 3D

   constructs were fabricated via in situ 3D printing. The in situ

   immobilized GOx/HRP in Gel II exhibited superactivity compared to free

   enzymes, which might be attributed to the synergistic effect of

   co-localized GOx and HRP minimizing the distances for mass transport

   between the gel and the bulk solution. This mechanically strong hybrid

   hydrogel maintained high reusability and thermal stability as well. In

   addition, in situ 3D cell culture was demonstrated, thus indicating that

   this biodegradable hybrid hydrogel is biocompatible with cells. The

   subsequent 3D cell printing further indicates that the hybrid hydrogel

   is a promising scaffold for bio-related applications such as

   biocatalysis and tissue engineering.

4. Liang, Meiying

   Liu, Xinhua

   Li, Wenjun

   Wang, Qigang

A Tough Nanocomposite Aerogel of Manganese Oxide and Polyaniline as an

   Electrode for a Supercapacitor

CHEMPLUSCHEM

VL 81

IS 1

BP 40

EP 43

DI 10.1002/cplu.201500399

PD JAN 2016

PY 2016

A tough aerogel electrode of manganese oxide and polyaniline was

   prepared by insitu gelation, freeze-drying, and heat treatment on carbon

   cloth. The porous structure endows the final aerogel electrode with high

   electrochemical performance even at high current density and excellent

   cycling stability.

5. Wu, Dongbei

   Gao, Yawei

   Li, Wenjun

   Zheng, Xiangning

   Chen, YongGui

   Wang, Qigang

Selective Adsorption of La3+ Using a Tough

   Alginate-ClayPoly(n-isopropylacrylamide) Hydrogel with Hierarchical

   Pores and Reversible Re-Deswelling/Swelling Cycles

ACS SUSTAINABLE CHEMISTRY & ENGINEERING

VL 4

IS 12

BP 6732

EP 6743

DI 10.1021/acssuschemeng.6601691

PD DEC 2016

PY 2016

Rare earth elements are an important strategic resource, and it is

   urgent that the rare earth industry continue to explore and develop

   novel separation methods and technologies. Herein, we fabricated an

   efficient semi-IPN alginate-clay-poly(n-isopropylacrylamide) (NIPAm)

   hydrogel by a frozen polymerization method with the help of UV light

   irradiation, where alginate was employed as the main adsorption

   functional compound. The as-prepared hydrogel exhibits tough,

   sponge-like hierarchical macroporous and reversible

   temperature-responsive characteristics. The maximum adsorption capacity

   of La is 182 mg/g for the hydrogel composition of S.0% NIPAm, 4.0%

   clay, and 3.0% alginate. The Langmuir isotherm fits the data very well,

   and the adsorption follows the pseudo-second-kinetic equation. The trace

   of La' ions can be effectively separated from the coexisting metal ions.

   After six repeated adsorption desorption cycles, no obvious deformation

   of the shape and or loss of adsorption capacity of the bulk hydrogel is

   found, but the stress level of the original hydrogel is significantly

   enhanced. Our results indicate that the green, sustainable, adsorbent

   hydrogel may serve as a versatile platform for recovery, separation, and

   purification of rare earth ions and suggest its potential applications

   in the fields of hydrometallurgy industries and wastewater treatment.

6. Wu, Dongbei

   Yi, Meirong

   Duan, Huiying

   Xu, Jingyan

   Wang, Qigang

Tough TiO2-rGO-PDMAA nanocomposite hydrogel via one-pot UV

   polymerization and reduction for photodegradation of methylene blue

CARBON

VL 108

BP 394

EP 403

DI 10.1016/j.carbon.2016.07.025

PD NOV 2016

PY 2016

We present a facile one-pot approach to fabricate tough TiO2-rGO-PDMAA

   nanocomposite hydrogel. Both synchronous polymerization of

   N,N-dimethylacrylamide (DMAA) monomer and reduction of graphene oxide

   (GO) sheets into porous hydrogel network are triggered by TiO2

   nanoparticles under the UV irradiation. The reduction of GO is

   accompanied color changes of the hydrogel from light-brown to black. The

   interpenetrating double hydrogel network between PDMAA chains and rGO

   can be fabricated at a considerable GO content, at which the hydrogel

   exhibits tough mechanical strength, good swelling ratio and quick

   self-recovery character. Benefiting from the excellent carrier mobility

   and large surface area of the rGO, our hydrogel has an improved photo

   degradation performance for methylene blue, suggesting its potential

   application in the wastewater treatment. (C) 2016 Elsevier Ltd. All

   rights reserved.

7. Cheng, He-li

   Feng, Qing-hua

   Liao, Chuan-an

   Liu, Yu

   Wu, Dong-bei

   Wang, Qi-gang

Removal of methylene blue with hemicellulose/clay hybrid hydrogels

CHINESE JOURNAL OF POLYMER SCIENCE

VL 34

IS 6

BP 709

EP 719

DI 10.1007/s10118-016-1788-2

PD JUN 2016

PY 2016

In this study, we chose corn stover hemicellulose for the preparation of

   hydrogels with admirable adsorption properties under mild alkaline

   conditions. Clay nanosheets were introduced to this system and

   hemicellulose/clay hybrid hydrogels were prepared. Morphological,

   mechanical properties and the methylene blue adsorption behaviors of the

   prepared hydrogels were studied. Results suggested that the addition of

   clay not only improved the mechanical strength of hemicellulose-based

   hydrogels, but also increased the adsorption capacity on methylene blue.

   Moreover, the adsorptions were confirmed to follow pseudo-second order

   equation for both gels with and without clay. The maximum adsorption

   capacities on methylene blue for hemicellulose-based hydrogels with or

   without clay reached 148.8 and 95.6 mg/g, respectively. These results

   implied that hemicellulose-based hydrogels could be used as promising

   adsorbents for the removal of methylene blue from waste water.

8. He, Hongjian

   Liu, Mingyu

   Wei, Junjie

   Chen, Ping

   Wang, Shilong

   Wang, Qigang

Hydrogel with Aligned and Tunable Pore Via Hot Ice Template Applies as

   Bioscaffold

ADVANCED HEALTHCARE MATERIALS

VL 5

IS 6

BP 648

EP 652

DI 10.1002/adhm.201500707

PD MAR 23 2016

PY 2016

9. Wei, Qingcong

   Xu, Wei

   Liu, Mingyu

   Wu, Qing

   Cheng, Liming

   Wang, Qigang

Viscosity-controlled printing of supramolecular-polymeric hydrogels via

   dual-enzyme catalysis

JOURNAL OF MATERIALS CHEMISTRY B

VL 4

IS 38

BP 6302

EP 6306

DI 10.1039/c6tb01792d

PD 2016

PY 2016

Hybrid hydrogels based on a guanidinium-containing oligopeptide are

   prepared via two dual-enzyme-triggered and simultaneous

   processes-self-assembly and polymerization. Furthermore, an extended

   time window is available for in situ viscosity-controlled 3D printing.

   In vivo hemostatic experiments elucidate that this

   guanidinium-containing hydrogel can accelerate the hemostasis process.

10. Qiao, Li

   Wang, Xia

   Gao, Yawei

   Wei, Qingcong

   Hu, Wen

   Wu, Lei

   Li, Pei

   Zhu, Rongrong

   Wang, Qigang

Laccase-mediated formation of mesoporous silica nanoparticle based redox

   stimuli-responsive hybrid nanogels as a multifunctional nanotheranostic

   agent

NANOSCALE

VL 8

IS 39

BP 17241

EP 17249

DI 10.1039/c6nr05943k

PD 2016

PY 2016

In this work, we designed a new hybrid nanogel with redox responsive

   polymer gel shells and mesoporous silica nanoparticles (MSNs) cores via

   laccase-mediated radical polymerization. The successful coating of the

   responsive gel shells on the MSNs was confirmed by the morphology and

   increased diameters of the particles as determined by transmission

   electron microscopy (TEM) and dynamic light scattering (DLS). As

   observed by scanning transmission electron microscopy (STEM) and energy

   dispersive X-ray spectroscopy (EDS), the presence of the element S

   around the MSNs further confirmed the formation of the gel shell. When

   loaded with doxorubicin (DOX), these hybrid nanogels had a significantly

   higher cumulative DOX release in a reductive environment than that found

   under physiological conditions. The MSNs with mesoporous channels were

   loaded with perfluorohexane (PFH) for ultrasound imaging, which was

   enhanced by the presence of the elastic gel shells.